To check or set Environment: Go to ORACLE DBA / General / Environment...
Connecting to database using sqlplus
$ sqlplus / as sysdba
$ sqlplus "/ as sysdba"
Using aliace
$ s
$ sqlplus /nolog
SQL> conn / as sysdba
$ sqlplus /nolog
SQL> conn sys@orcl as sysdba
Connect remotely using oracle client installed on the local computer
$ sqlplus sys/sys_password@IPADDR/INSTANCE_NAME as sysdba
$ sqlplus sys/sys@10.0.0.1/orcl as sysdba
$ export NLS_LANG=AMERICAN_RUSSIA.AL32UTF8 # set codepage, if you have troubles with reading of the output messages (unreadable characters)